High pressure infrared spectroscopy study on C60∗CS2 solvates
نویسندگان
چکیده
منابع مشابه
In situ high-pressure study of diborane by infrared spectroscopy.
As the simplest stable boron hydride in its condensed phase, diborane exhibits an interesting structural chemistry with uniquely bridged hydrogen bonds. Here we report the first room-temperature infrared (IR) absorption spectra of solid diborane compressed to pressures as high as 50 GPa using a diamond anvil cell. At room temperature and 3.5 GPa, the IR spectrum of diborane displays rich sharpl...
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The single-crystal X-ray structure of Ru(3)(CO)(12) is reported at 8 pressures ranging from 1 atm (0.0 GPa) to 8.14(5) GPa. Although intramolecular bonding parameters remain relatively constant, intramolecular and intermolecular nonbonding contact distances decrease by an average of 4% and 15%, respectively. At 8.14 GPa, O...O, C...O, and C...C intermolecular distances as short as 2.54(4), 2.64...
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Changes in the conformations of conjugated molecules affect the optical and electronic properties significantly. Hydrostatic pressure has been used to probe the conformations of biphenyl (C12H10) and deuterated biphenyl (C12D10) at liquid-helium temperatures. Infrared ~IR! spectra of these materials have been taken up to a pressure of 2 GPa. A disappearance of certain IR absorption peaks has be...
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We have developed infrared spectromicroscopic system which works under high pressure up to 20GPa by using a diamond-anvil-cell combined with brilliant infrared radiation source from SPring-8, the storage ring facilities at Harima in Japan. This system is available from far-infrared to visible region. As a typical example, the optical reflection spectra of a polycrystalline CuIr2Se4 were measure...
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B. Chen, D. V. S. Muthu, Z. X. Liu, A. W. Sleight, and M. B. Kruger Department of Physics, University of Missouri, Kansas City, Missouri 64110 Department of Physics, Indian Institute of Science, Bangalore 560 012, India Geophysical Laboratory and Center for High Pressure Research, Carnegie Institution of Washington, Washington, D.C. 20015 Department of Chemistry, Oregon State University, Corval...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 2017
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2016.11.047